Hydrothermal Synthesis of MoS2/SnS2 Photocatalysts with Heterogeneous Structures Enhances Photocatalytic Activity.

Abstract

The use of solar photocatalysts to degrade organic pollutants is not only the most promising and efficient strategy to solve pollution problems today but also helps to alleviate the energy crisis. In this work, MoS2/SnS2 heterogeneous structure catalysts were prepared by a facile hydrothermal method, and the microstructures and morphologies of these catalysts were investigated using XRD, SEM, TEM, BET, XPS and EIS. Eventually, the optimal synthesis conditions of the catalysts were obtained as 180 °C for 14 h, with the molar ratio of molybdenum to tin atoms being 2:1 and the acidity and alkalinity of the solution adjusted by hydrochloric acid. TEM images of the composite catalysts synthesized under these conditions clearly show that the lamellar SnS2 grows on the surface of MoS2 at a smaller size; high-resolution TEM images show lattice stripe distances of 0.68 nm and 0.30 nm for the (002) plane of MoS2 and the (100) plane of SnS2, respectively. Thus, in terms of microstructure, it is confirmed that the MoS2 and SnS2 in the composite catalyst form a tight heterogeneous structure. The degradation efficiency of the best composite catalyst for methylene blue (MB) was 83.0%, which was 8.3 times higher than that of pure MoS2 and 16.6 times higher than that of pure SnS2. After four cycles, the degradation efficiency of the catalyst was 74.7%, indicating a relatively stable catalytic performance. The increase in activity could be attributed to the improved visible light absorption, the increase in active sites introduced at the exposed edges of MoS2 nanoparticles and the construction of heterojunctions opening up photogenerated carrier transfer pathways and effective charge separation and transfer. This unique heterostructure photocatalyst not only has excellent photocatalytic performance but also has good cycling stability, which provides a simple, convenient and low-cost method for the photocatalytic degradation of organic pollutants.