Hydrothermal Synthesis of MnO2 Microspheres and Their Degradation of Toluene.

Abstract

Various urchin-like MnO2 materials were obtained with a facile hydrothermal method through controlling the Mn precursor, reaction time, and reaction temperature. The property of MnO2 materials was characterized by scanning electron microscopy, X-ray diffraction, and H2 temperature-programmed reduction. The results showed that the Mn precursor could significantly impact the morphology of as-prepared MnO2. When the precursor was Mn(CH3COO)2·4H2O, the MnO2 morphology consisted of tennis-like microspheres assembled by nanorods. While the precursor was MnCl2·4H2O, the sample morphology was a chestnut shell, and the samples were sea urchin microspheres, as the precursor was MnSO4·H2O. At the same time, the morphology of MnO2 was affected by hydrothermal time and temperature. The nanoneedles on the microsphere surface gradually lengthened with increasing hydrothermal time and hydrothermal temperature, until nanowires were formed. MnO2 crystallinity was also influenced by hydrothermal temperature. It was γ-MnO2 as the temperature was 50 and 80 °C while evolved to be α-MnO2 and β-MnO2 when the temperature increased to 140 °C. As MnO2 (MnO2-1 h, MnO2-2 h, MnO2-4 h, and MnO2-6 h) was prepared to degrade toluene, all the samples could completely catalyze toluene at the temperature of 225 °C. However, the MnO2-4 h showed the best catalytic effect at a lower temperature.