Abstract
Hydroxyapatite (HAP) rods were synthesized from dicalcium phosphate anhydrous (CaHPO 4, DCPA) and calcium carbonate (CaCO 3) by the hydrothermal method from 120 to 180 °C. Both cuttlebone (aragonite polymorph of CaCO 3) and CaCO 3 chemical (calcite polymorph of CaCO 3) were used as CaCO 3 sources. The nucleation and growth of HAP rods mainly occurred on DCPA particles, while some HAP rods also grew from aragonite particles. The nucleation and growth of β-tricalcium phosphate (β-TCP) particles on the surface of calcite particles were observed at the beginning of the reaction of DCPA and calcite, and some HAP rods were also found to grow out of β-TCP particles. After the hydrothermal reaction at 140 °C for 24 h, most products are HAP with a small amount of β-TCP synthesized as a byproduct. The HAP rods synthesized were ∼200 nm in width and several microns in length. The reaction mechanism and growth process of HAP rods are discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.