Abstract
Dicalcium phosphate dihydrate (DCPD) and anhydrous dicalcium phosphate (DCPA) extracted from a by-product in a manufacture of gelatin from bovine bone are used as starting materials for the hydrothermal synthesis of hydroxyapatite (HA) at temperatures of 160 and 200 degrees C under vapor pressures of 1 and 2 MPa, respectively. The suspension of DCPA with water gives a mixture of DCPA and HA as product but after adjusting the Ca/P molar ratio to 1.50 and 1.67 by addition of Ca(OH)(2), a single phase of HA with needle-like crystals is obtained. DCPA whiskers are produced in the suspension of DCPD with water but, on addition of Ca(OH)(2), the product obtained is again, a mixture of DCPA and HA. The coexistence of DCPA and HA is observed not only in the acidic region at pH 4.6 which is close to the known quasi-invariant point but also in the basic region at pH 12.3. Without addition of Ca(OH)(2) to the system, the complete conversion of DCPA or DCPD to HA is not possible.
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