Abstract

We report a hydrothermal synthesis of a hybrid structure between gold nanoparticles and a metal organic framework, ZIF-8 (abbreviated as Au@ZIF-8). Au nanoparticles encapsulated in polyvinylpyrrolidone (PVP) was employed as seeds to grow the framework of ZIF-8. We controlled the position and concentrations of Au nanoparticles on ZIF-8 crystal by adjusting the volume of Au nanoparticles dissolved in DI water during the growth of ZIF-8. Morphology, structure, distribution of the hybrid structure were investigated by transmission microscope, powder xray diffraction, and diffuse reflectance UV-Vis spectroscopy. We tested out catalytic properties of Au@ZIF-8 through the reaction of 2-nitrophenol and NaBH4.

Highlights

  • GI I THI UV t li u khung h u c kim lo i (Metal Organic Frameowork, MOF) là v t li u c t o thành b i liên ktcacm kim lo i vô c (metal cluster) v i các cunihuc (organic linker)

  • We report a hydrothermal synthesis of a hybrid structure between gold nanoparticles and a metal organic framework, ZIF-8 (abbreviated as Au@ZIF-8)

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Summary

GI I THI U

V t li u khung h u c kim lo i (Metal Organic Frameowork, MOF) là v t li u c t o thành b i liên ktcacm kim lo i vô c (metal cluster) v i các cunihuc (organic linker). Kim lo i vàng kích th c nano có tính c ng h ng b m t, di n tích bmtln khi kthpvivt li u MOF s có th h ng n tìm th y v t li u có c ng h ng t vùng quang h c [18, 19] ho c v t li u quang xúc tác phân hu các h p ch t h u c [20] tu thu c vào v trí c a h t nano vàng trong tinh th v t li u MOF. Trong nghiên c u này, chúng tôi báo cáo quy trình t ng h p c u trúc lai c a h t nano vàng và v t li u khung c kim ZIF-8 (ZIF: Zeolitic Imidazole Framework); và th nghi m kh n ng ph n ng phân hu h p ch t h u c 4-nitrophenol trong i u ki n th ng

V T LI U VÀ PH NG PHÁP
K T LU N

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