Abstract
The complete detoxification of harmful dyes and antibiotics from aqueous solution is essential for environmental remediation. The present work focuses on a facile hydrothermal synthesis of a cadmium sulfide (CdS) photocatalyst using thioacetamide as a sulfur source. The synthesized CdS showed a hexagonal phase with an energy gap of 2.27 eV, suggesting the promising visible-light-responsive semiconducting photocatalyst. The photoactivity of the prepared CdS was investigated by evaluating the degradation of the Reactive red 141 (RR141) dye, Congo red (CR) dye, and ofloxacin (OFL) antibiotic. After only 180 min of solar light illumination, a high performance of 98%, 97%, and 87% toward degradation of RR141, CR, and OFL was obtained. The photodegradation of the pollutants agrees well with the first-order kinetic model. The rate constant of 0.055 min-1, 0.040 min-1, and 0.026 min-1, respectively, was reported toward degradation of RR141, CR, and OFL. Photogenerated holes and hydroxyl radicals play a vital role in removing toxic organic contaminants. The chemical stability of the prepared CdS was also confirmed. The synthesized CdS photocatalyst still maintains high photocatalytic performance even after five consecutive cycles of use, indicating its excellent cycling ability. The present research shows a facile route to fabricate a CdS photocatalyst to completely detoxify harmful organic pollutants, including dyes and antibiotics, in the environment.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.