Abstract
The hydrothermal synthesis of V 2O 5, Ag 2O and H 2L (H 2L = pyridine-2,6-dicarboxylic acid) in water at 180 °C for 72 h yields a novel 2D coordination polymer [VAgLO 2] n ( 1). Each V center chelates to a tridentate ligand L, while the tetrahedral conformation of Ag center consists of four O atoms. V and Ag polyhedra alternate by either carboxyl or oxo bridges to further form a unique 3d–4d heterometal-based 2D grid motif.
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