Abstract
A series of pure and aluminum (Al) doped WO3 powders were synthesized at low temperature. The as synthesized materials have been characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), ultraviolet–visible (UV–VIS) spectroscopy and color difference meter, respectively. A relation was found between the color difference and the UV–VIS photochromic activity. Moreover, the optical band gap of the as-prepared powder narrowed due to the appearance of impurity levels as the Al3+ ions migrated into the WO3 crystal lattice. Some rod-like particles have been found to decrease with the increase of Al concentration. An optimum Al concentration was found to be 0.25% to present the best UV-light induced photochromic activity. The mechanism of photochromic process of the Al-doped WO3 powders has been discussed in detail based on the characterization results.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.