Abstract
An exploration of the cadmium-citrate system under hydrothermal conditions, has led to the isolation of a novel framework [Cd 3(H 2O) 2(C 6H 5O 7) 2] n 1. This compound features a novel 2D undulated sheet containing infinite double-stranded helical chains, which is unique among metal-citrate system identified so far. Crystal data for compound 1: Monoclinic, Space group P2 1 / c, a=6.0974(12) Å, b=15.271(3) Å, c=9.781(2) Å, β=102.74(3)°, V=888.3(3) Å 3, Z=2. Other characterizations by elemental analysis, IR and TG are also described.
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