Hydrothermal synthesis and structural investigation of silver magnesium complex of benzenehexacarboxylic acid (mellitic acid), Ag 2Mg 2[C 6(COO) 6] · 8H 2O with two-dimensional layered structure

Abstract

Crystal and molecular structure of silver magnesium mellitate, Ag 2Mg 2[C 6(COO) 6] · 8H 2O, was synthesized hydrothermally and characterized by X-ray structure analysis. The complex crystallizes in the monoclinic system, space group P2/ n, with unit cell dimensions of a=7.4347(2), b=9.9858(2), c=14.4248(3) Å, β=99.2429(5)°, V=1055.01(4) Å 3, and Z=2. The structure was solved and refined to R=0.036 ( R w=0.045) for 1707 independent reflections [ I o>2 σ( I o)]. The Ag cations are coordinated by six carboxylic oxygen atoms of mellitate anions with composition of [C 6(COO) 6] 6− on the (1 0 1) plane; each mellitate anion linking three neighboring Ag distorted trigonal prisms produces a two-dimensional layered structure parallel to (1 0 1). The Mg cations, which are coordinated by four water molecules and two carboxylic oxygen atoms, are intercalated between the two-dimensional layer stacks. The carboxylate group coordinated to Mg and Ag cations serve as a tridentate ligand in that structure. The number of water molecules incorporated into the mellitate compound is controlled mainly by ionic radii of metal cation in the structure. Furthermore, the ionic radii of metal cations in the mellitate compound play an essential role in arrangement of mellitate anions in the structure, whether as a one-dimensional infinite chain, a two-dimensional layered structure, or a three-dimensional framework structure.