Abstract

AbstractThe cover picture shows the formation of water‐soluble ruthenium derivatives of heteropolytungstates. Depending on the experimental conditions, the authors were able to isolate the new [{PW11O39}2{(HO)RuIV–O–RuIV(OH)}]10– anion. This complex, which has been obtained under hydrothermal conditions, contains an {(HO)RuIV–O–RuIV(OH)} moiety that links two monovacant [α‐PW11O39]7– subunits. It is one of the rare examples of a polyoxometalate that contains noble‐metal cations in a high oxidation state. The strategy for the synthesis and the full characterization in the solid‐state and in solution of this compound are discussed in the article by A. Proust et al. on p. 2137 ff.

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