Abstract
Three new tungsten(VI) oxide hybrid materials, [WO3(pyz)0.5] (pyz=pyrazine) 1, [WO3(bpy)0.5] (bpy = 4,4′-bipyridyl) 2 and [W3O10(enH2)] 3, have been hydrothermally synthesized: 1 and 2 exhibit covalent/coordination hybrid framework connectivities while the structure of 3 consists of novel layers comprised of distorted {WO6} octahedra linked through edge- and corner-sharing interactions.
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