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Abstract
Hydrothermal reaction of CuCN, K 3[Fe(CN) 6] and 1,10-phenanthroline affords a novel cyanide-bridged copper(I) coordination polymer [Cu 3(CN) 3(phen)] n ( 1). The complex displays an interesting one-dimensional neutral double helical framework with (phen)Cu–CN– side-arms as interchain bridges. The double helical chains are close packed in a parallel fashion, and the phen ligands stack in an interpenetrating mode, which leads to π–π interactions between parallel phen planes. The thermal stability and fluorescent property have also been investigated.
Published Version
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