Abstract
Abstract A new one-dimensional molybdenum oxide compound with manganese-o-phen subunit: [Mn(o-phen)(H2O)MoO4]·H2O (1) (o-phen=o-phenanthroline) was synthesized by thehydrothermal reaction of Na2MoO4·2H2O, MnSO4·H2O, oxalic acid, o-phenanthroline (o-phen) and water. Its structure was determined by elemental analyses, ESR spectrum, TG analysis, IR spectrum and single-crystal X-ray diffraction. Compound 1 crystallizes in triclinic system, space group P-1 with a=7.0401(2) A, b=10.4498(2) A, c=10.5720(2) A, α=73.26(7)°, β=83.34(8)°, γ=77.33(9)°, V=725.5089(0) A3, Z=2, and R1=0.0322 for 2337 observed reflections. Compound 1 exhibits one-dimensional chain structure. The chains are linked up via hydrogen bonding to 2D layers, which are further assembled through π–π stacking interactions to a 3D supermolecular structure.
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