Hydrothermal synthesis and characterization of micro to nano sized carbon particles

Abstract

Experiments under hydrothermal conditions were carried out to study the formation of elemental carbon through the decomposition of β-Silicon carbide (β-SiC) in the presence of organic compounds. The organic compounds were known to dissociate at low P-T conditions and produce the C–O–H supercritical fluids, which will have great influence on the decomposition of β-SiC. These hydrothermal runs under the influence of supercritical fluids will not only help in dissociating the silicon carbide into SiO2 and free elemental carbon but also control the type of carbon phase formation. The Scanning Electron Microscopic (SEM) studies of the run products indicate the formation of the micron sized carbon particles having characteristic shapes like spherical/ovoid, scaly with metallic lustre and in some runs we find the formation of nano sized octahedral crystallites. Micro Raman study of these carbon particles reveals that bulk of the carbon formed in these runs were disordered / sp2–hybridized carbon but we also noticed the formation of black scales over the spherical particles and the octahedral crystallites which exhibits the sp3-hybridization having the characteristic sharp band at 1332 cm-1, comparable to that of diamond powder. The octahedral crystallites are formed at the inner walls of the hollow spherical carbon particles. In any of the experimental runs we haven't used either the metal catalysts or the diamond seed with the charge material. Thus, the nucleation and formation of nano sized octahedral crystallites of diamond (sp3-hybridized carbon) in the present study at lower P-T conditions compared to that of its formation in nature is a significant breakthrough in the study of diamond synthesis.