Abstract
Abstract Na+ was used as template in the synthesis of tunnel manganese oxides from a layered manganese oxide under hydrothermal conditions. Two types of tunnel manganese oxides were obtained by the hydrothermal reaction. The manganese oxide with a one-dimensional (2 × 4) tunnel structure formed under low temperature conditions, and Na0.44MnO2 with a one-dimension complex tunnel structure under high temperature conditions. The mechanism of the transformation reaction can be explained from the structures of the products and template size.
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