Hydrothermal route-enabled synthesis of sludge-derived carbon with oxygen functional groups for bisphenol A degradation through activation of peroxymonosulfate

Abstract

A considerable amount of sewage sludge (SS) is generated from wastewater treatment process, which is hazardous to the environment and in urge to be disposed. In this study, for the first time, we prepared carbocatalyst with abundant surface oxygen functional groups using the hazardous waste of SS as precursor via a facile hydrothermal coupled pyrolysis process. The hydrothermal treatment was found to be crucial for enhancing the oxygen content of sludge carbon (SC), most of which existed as ketonic groups. Catalytic performances of the developed SCs were examined by activating peroxymonosulfate (PMS) to degrade bisphenol A (BPA). Sample with more ketonic group performed better for BPA degradation. Under optimal reaction conditions, 100 % of BPA and 69.53 % of TOC could be removed in 20 min. Singlet oxygen (1O2) was suggested to be the main reactive oxygen species for degrading BPA and a BPA degradation pathway was proposed. The BPA solution showed decreased bio-toxicity after the oxidation process according to the acute ecotoxicity test. This study demonstrated the importance of surface functional groups on carbocatalyst for advanced oxidation process, which could be induced by a facile hydrothermal treatment. The feasibility of utilizing hazardous SS for advanced carbocatalyst fabrication was also revealed.