Abstract
Active thermal vents of the Piip submarine volcano were studied in 1990 from aboard submersibles MIR 1 and 2. Samples of free gas and hydrothermal deposits were collected in the areas of thermal fluid discharge. Mineralogical, isotopic and microprobe studies of samples have shown, as the hydrothermal system cools, the high-temperature anhydrite association displayed at the surface is substituted by calcite-barite and later by calcite-barite-sulfide assemblages. The chemical and isotopic composition of gas and carbonates indicates the significant role of hydrocarbons from the sedimentary layers which, during the low-temperature stage, stimulate the processes of bacterial sulphate reduction. The evolution of a simular hydrothermal system is traced in the Great Caucasus barite deposits.
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