Hydro-Thermal Fatigue of Polymer Matrix Composite Biomaterials.

Daniel Pieniak,Leszek Gil,Grzegorz Bartnik,Agata Walczak,Paweł Lonkwic,Aneta Krzyzak,Agata M Niewczas,Krzysztof Przystupa

doi:10.3390/ma12223650

Abstract

This study discusses a quantitative fatigue evaluation of polymer–ceramic composites for dental restorations, i.e., commercial (Filtek Z550) and experimental Ex-nano (G), Ex-flow (G). Their evaluation is based on the following descriptors: mechanical strength, elastic modulus and strain work to fracture. Supposed to reflect factors of environmental degradation conditions, thermal fatigue was simulated with a special computer-controlled device performing algorithms of thermocycling. The specimens intended for the strength test underwent 104 hydro-thermal fatigue cycles. This procedure of thermocycling was preceded by aging, which meant immersing the specimens in artificial saliva at 37 °C for 30 days. The strength tests after aging only and after aging and thermocycles were performed in line with the three-point flexural strength (TFS) test, specified in ISO 4049, and the biaxial flexural strength (BFS) test, specifically piston-on-three-ball in accordance with ISO 6872. Based on the results, it can be stated that composites with higher volume content of inorganic particles after aging only show higher strength than materials with lower filler particle content. For example, the average flexural bending strength of the Ex-flow (G) composite was about 45% lower than the value obtained for the Ex-nano (G) material. The residual strength after thermocycles is significantly lower for the experimental composites, whereas a smaller decrease in strength is recorded for the commercial composites. Decreases in strength were about 4% (Filtek Z550), 43% (Ex-nano (G)), and 29% (Ex-flow (G)) for the BFS test; and about 17% (Filtek Z550), 55% (Ex-nano (G)), 60% (Ex-flow (G)) for the TFS test. The elastic modulus of the experimental composites after only aging is higher (about 42%) than that of the commercial composite, but the elastic modulus of the commercial composite increases significantly after thermocycling. A descriptor known as strain work to fracture turns out to be a good descriptor for evaluating the hydro-thermal fatigue of the tested polymer–ceramic composites.

Highlights

Composite materials are used in a variety of applications due to their special properties and benefits for transferring loads in biomechanical systems [1,2,3,4,5]
The results of the biaxial flexural strength (BFS) test with the following quantities are given in Table 2: FBI —maximum force, The results of the BFS test with the following quantities are given in Table 2: FBI—maximum dL (FBI )—specimen’s deflection under the maximum force, FFract —damage force, dL(FFract )—maximum force, dL (FBI)—specimen’s deflection under the maximum force, FFract—damage force, dL(FFract)—
It was indicated that the experimental composites, i.e., Ex-nano (G) and Ex-flow (G), are less durable than the commercial composite Z550 due to hydro-thermal fatigue

Summary

Introduction

Composite materials are used in a variety of applications due to their special properties and benefits for transferring loads in biomechanical systems [1,2,3,4,5]. Polymer–ceramic composites, more precisely light-cured polymer matrix ceramic composites (LC PMCCs), are mainly applied as fillings in human teeth, but are applied in structures for permanent composite dental prostheses like crowns and bridges, dentures, and partial dentures, as well as temporary and permanent splinting [5,6]. Their mechanical properties, which are important in the operational environment, depend on various factors, such as the materials’ microstructure, failure mechanisms and environmental effects [7,8,9]. All new LC PMCCs should be tested in order to determine their properties

Objectives

Methods

Results

Conclusion