Hydrothermal alkaline synthesis and release properties of silicon compound fertiliser using high-ash coal slime.

Abstract

High-ash coal slime is difficult to utilise as a boiler fuel, and its accumulation results in environmental pollution. In this study, we describe a new method for the preparation of high-ash coal slime silica compound fertiliser (HASF) using CaO-KOH mixed hydrothermal method to optimize the utilization of this industrial waste and relieve the pressure on the fertiliser industry. The coal slime (D0) used in this study and its dry basis ash content by 1mol/L and 4mol/L sulfuric acid pre-activation (D1, D4) were greater than 85%. The effective silicon content of D0, D1, and D4 silica compound fertilisers reached 30.24%, 31.24%, and 17.35%, respectively, and the sums of effective silica-calcium-potassium oxides were 57.28%, 58.87%, and 48.16%, respectively, under the optimal reaction conditions of 230°C, 15h, and 1mol/L KOH, which met the market requirements, as determined using single-factor experiments. We used XRD, FTIR, and SEM-EDS analysis techniques to demonstrate that tobermorite and leucite were the main mineral phases of the compound fertiliser, and activated coal slime D4, which contains only quartz single crystals, required more demanding reaction conditions in the synthesis reaction. Subsequently, the cumulative release pattern of HASF silica was well described by the power function equation via repeated extraction and dissolution experiments, with the dissolution rate following D4 > D1 ≈ D0. Furthermore, 4mol/L sulfuric acid pre-activation resulted in the enrichment of HASF combined with organic matter and increased the slow-release rate of HASF silica. Thus, the synthesized HASF could have potential application prospects in soil improvement and fertilisation.