Hydrostatic pressure dependence of the fundamental bandgap of InN and In-rich group III nitride alloys

Abstract

We report studies of the hydrostatic pressure dependence of the fundamental bandgap of InN, In-rich In1−xGaxN (0<x<0.5) and In1−xAlxN (x=0.25) alloys. The bandgap shift with pressure was measured by optical absorption experiments with samples mounted in diamond anvil cells. The pressure coefficient is found to be 3.0±0.1 meV/kbar for InN. A comparison between our results and previously reported theoretical calculations is presented and discussed. Together with previous experimental results, our data suggest that the pressure coefficients of group III nitride alloys have only a weak dependence on the alloy composition. The photoluminescence signals appear to yield significantly smaller pressure coefficients than the bandgap from absorption measurements. This is due to emission associated with highly localized states. Based on these results, the absolute deformation potentials of the conduction and valence band edges are estimated.