Abstract
Abstract In the presence of a simple combined catalyst of a tungstate monomer (TBA2WO4, TBA: tetra-n-butylammonium) and rhodium acetate (Rh2(OAc)4), hydrosilylation of various types of substances including ketone, aldehyde, carbon dioxide, alkene, nitrile, and furan derivatives efficiently proceeded, affording the corresponding hydrosilylation products in moderate to high yields (≥63% yields). In addition, the present system was also applicable to the one-pot reduction of benzamide to benzylamine (95% yield).
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