Abstract
The hydrosilylation of olefins with allyldicholorosilane in the presence of chloroplatinic acid diluted with isopropanol gave allylalkyldichlorosilanes, retaining the allyl group. When the olefin was used in fivefold excess or more relative to allyldichlorosilane, allylalkyldichlorosilanes were obtained in good yields (63–89%), and the formation of double hydrosilylation products was reduced to less than 6%. The isomerization of allylsilane to 1-propenylsilane was suppressed by lowering reaction temperatures below 100°C. This hydrosilylation of olefins with allyldichlorosilane is a good synthetic route to an allyl group containing organodichlorosilanes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
