Abstract
Summary The ruthenium complex [RuCl2(PPh3)3] catalyses the reaction of triethylsilane with ketones, RR′CO, and aldehydes, RCHO, to give the hydrosilylation products RR′CHOSiEt3 and RCH2OSiEt3, respectively, but it is not as effective a catalyst as [RhCI(PPh3)3]. The complex [RuCIH(PPh3)3] was obtained by treatment of [RuCl2(PPh3)3] with triethylsilane, and [RhCl(PPh3)2(CO)] was isolated from reaction between p-methoxybenzaldehyde and triethylsilane catalysed by [RhCl(PPh3)3].
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