Abstract
AbstractWe have developed a hydrosilylation reaction of alkenes using 1,1,3,3‐tetramethyldisiloxane (TMDS) as a surrogate for Me2SiH2 in the presence of NaOMe, catalyzed by a bench‐stable nickel‐pincer complex supported by a monoanionic O,N,P‐tridentate ligand. The reaction of styrene derivatives proceeds smoothly under mild reaction conditions to provide the hydrosilylated products in high yields with high Markovnikov selectivity. This protocol shows a wide substrate scope and is compatible with a wide range of functional groups. Secondary hydrosilanes are also suitable under the present reaction conditions and furnish the desired products in high yields.
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