Abstract
The reaction of HSiCl3 with 2-[N-(2,6-diisopropylphenyl)iminomethyl]indolyl lithium (DippIMIndLi) provided disubstituted (DippAMInd)(DippIMInd)SiCl (2), where one imino moiety of DippIMInd ligand was reduced to amino group by Si-H fragment. In contract the reaction of HSiCl3 with 2-[N-(2,6-diisopropylphenyl)iminomethyl]phenyl lithium (DippIMPhLi) provided stable CHN→Si coordinated silane (DippIMPh)SiHCl2 (3). Heating of the toluene solution of 3 provided the hydrosilylated compound (DippAMPh)SiCl2 (4). It has been demonstrated that the rate of CHN imino group reduction strongly depends on type of the anionic ligand.
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