Hydrophobic surface modification toward highly stable K2SiF6:Mn4+ phosphor for white light-emitting diodes

Abstract

K2SiF6:Mn4+ phosphor is well known for its excellent red emission performance which is vital for improving the color rendering of white light-emitting diodes. However, the poor moisture resistance limits its application in optical devices. In this paper, K2SiF6:Mn4+ phosphor is coated with an inorganic hydrophobic protective layer to obtain good moisture resistance. Chemical vapor deposition method was used to decompose acetylene at high temperature, and the generated nanoscale carbon layer worked as a hydrophobic protective coating on the surface of the phosphor. Microstructure, compositions and properties of the synthesized K2SiF6:Mn4+@C phosphor were investigated in detail. It is found that most of the deposited carbon is coated on the surface of phosphor crystals in amorphous state. The carbon atoms are bonded with the fluorine element in K2SiF6:Mn4+ phosphor, forming carbon-fluorine (C–F) covalent bonds. The moisture resistance of K2SiF6:Mn4+@C phosphor is improved owing to the protection of the hydrophobic carbon. The relative emission intensity of K2SiF6:Mn4+@C phosphor could maintain 73% of the initial luminous intensity after immersing in the aqueous solution at room temperature for 8 h, whereas K2SiF6:Mn4+ phosphor without carbon coating was only 0.7% remaining of the initial value under the same conditions.