Hydrophobic hyper-cross-linked polymer shells encapsulating dispersed nanoscale CuS boosting mercury immobilization

Abstract

Metal sulfides (MSs) hold significant promise for environmental remediation but are hindered by their low accommodation capacity and poor water resistance. Herein, this work reports a hybrid strategy to address these limitations by assembling highly dispersed CuS nanoparticles within the hyper-cross-linked polymer (HCP). Benefiting from the super-hydrophobicity and well-developed porosity of HCP, alongside the high dispersion and multiple active sites of CuS nanoparticles, the resultant CuS@HCP exhibits exceptional water resistance, enhanced surface area, high mass transfer ability, and substantial Hg0 adsorption capacity. The Hg0 adsorption capacity (Q90) of CuS@HCP3 reaches 1.25 and 1.391 mg/g under N2 and simulated flue gas, respectively. Notably, the normalized Q90 of coated CuS surpasses that of pristine CuS by 25-fold under N2 + 15 % H2O and its durability outstrips most previously reported mineral sulfides even in complex simulated flue gas. Universal research confirms MSs@HCP (M = Zn, Sn, and Fe) equally demonstrate over 15-fold increment in Hg0 retention under high humidity conditions compared to the pristine MSs. Such HCP hybrid strategy universally and effectively optimizes the accommodation capacity and water resistance of MSs, endowing MSs@HCP broad application prospects.