Hydrophilic porous activated biochar with high specific surface area for efficient capacitive deionization

Abstract

Porous carbon electrode materials were prepared by carbonization and alkali activation from three natural porous biomasses, lotus petiole (LP), sunflower plate (SP), and lotus seedpod (LS). The pore structure, surface characteristics, and electrochemical properties of the three activated biochars were investigated and related to their CDI performance. The results indicated that the three activated biochars were hydrophilic and negatively charged, with a high specific surface area and an abundance of micropores. Due to the best surface wettability, highest specific capacitance, and shortest charge-discharge time, lotus petiole-based activated biochar (LPCK) had the highest electrosorption capacity of 8.67mg·g-1 and faster desalination rate of 0.24mg·g-1·min-1. Cyclic voltammetry and adsorption kinetics results indicate that the double-layer electrostatic adsorption mechanism dominated the CDI processes of the three activated biochars. The use of three biomass wastes provides low-cost, eco-friendly, and sustainable materials for the development of CDI electrodes.