Abstract

The title compound, (H3O)[Cu2Cl(C12H8N2)4][W6O19]·H2O, has been synthesized hydro­thermally. The structure contains a dicopper(I) complex cation comprising two [Cu(phen)2]+ units bridged by a chloride ion lying on a twofold rotation axis, a Lindquist isopolyanion, [W6O19]2−, lying on a centre of inversion, one hydro­nium cation, and one uncoordinated water mol­ecule per formula unit.

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