Hydrometallurgy of precious metals recovery

Abstract

The hydrometallurgical process for the treatment of gold and silver ores remained unchanged for the first 70 years of this century, and consisted essentially of leaching in cyanide solution followed by solid-liquid separation, with the solid residues being washed as efficiently as possible, and the leach liquor being treated by zinc cementation to recover the precious metals. White this process is generally extremely efficient and fairly cheap, it does have limitations in the treatment of low-grade ores and certain complex ore types. For example, ores with a high content of clay or other soft, fine minerals are usually difficult to filter, and losses of soluble gold or silver in the residues can be unacceptably high. In other situations, where the precious metal host rock contains high concentrations of sulphides such as pyrite or arsenopyrite, for example, or base-metal oxides or carbonates, the traditional process often suffers from poor gold recovery (due to encapsulation of the precious metals in the sulphides) or high cyanide consumption, or both of these. Whereas these occurrences were fairly rare (or were avoided!) in the first half of this century, they are now assuming great importance, and each year a higher percentage of world gold production derives from sources such as these.A number of new hydrometallurgical processes have been developed and implemented in the gold industry in the last 20 years, and these have transformed gold processing into a chemical “high tech” industry, and have allowed increasingly complex ore types and progressively lower grades of ore to be treated economically. As a result, in a period when gold production might have been expected to decline, world-wide production has almost doubled over the two decades.This paper describes the traditional cyanidation and zinc cementation processes, but focuses on the new developments in the industry. In particular, new leaching technologies such as heap leaching for low-grade ores and pressure leaching for refractory sulphide ores are discussed, as well as the carbon-in-pulp and carbon-in-leach processes that have effectively replaced filtration and countercurrent decantation on almost every gold plant built since 1980. Some emerging technologies such as bacterial leaching and resin-in-pulp are also discussed briefly.