Abstract
Nanosized titanium(IV) oxide in the anatase form was synthesized by hydrolysis of titanium(IV) alkoxide in toluene with water that was dissolved from the gas phase at high temperatures (150−300 °C). With elevation of the reaction temperature and an increase of the reaction time, the crystallite size of the anatase was gradually increased from several to ca. 20 nm in the present reaction medium. Corresponding to the crystal growth, surface areas of the products were decreased while the rutile-transformation temperature became higher and the thermal stability was improved. For example, the product obtained by the reaction at 300 °C for 24 h possessed a surface area of 54 m2 g-1 even after calcination at 900 °C and began to transform to the rutile phase at around 1000 °C.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
