Abstract
Hydrolysis of radicals and molecules of some ethers
Highlights
The radiolysis of aqueous solutions of tributylphosphate, butylacetate and isobutylacetate under the γ-radiation in an argon atmosphere has been studied
It has been shown that the rate constants of hydrolysis of radicals are ~ 108 times higher than the rate constants of hydrolysis of ester molecules
S. Formation of Isomers in the Radiolysis of Aqueous Solutions of Alcohols // High Energy Chemistry, 2017, vol 51, no 4
Summary
The radiolysis of aqueous solutions of tributylphosphate, butylacetate and isobutylacetate under the γ-radiation in an argon atmosphere has been studied. При радиолизе водных растворов ТБФ в нейтральной среде образуются два основных типа радикалов: 1) CH3CH2CH2–СН–О–P(O)(OC4H9)2 с выходом 3,3 и 2) (C4H9O)3P– O– с выходом 2,7 молекула/100 эВ. Образование непосредственно молекул бутанола-1 возможно при гидролизе радикалов второго типа: (C4H9O)3P– O– + Н2О → C4H9OН + (C4H9O)2(HO)P– O– . Добавление в щелочной раствор ТБФ пропанола-2 (0,1 м/л), как акцептора ОН и Н радикалов, практически не снижало выход бутанола-1, который составил 2,5 молекула/100 эВ.
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
