Abstract
Abstract The hydrolytic reaction of nickel ion was studied at 25°C in an aqueous 3m sodium chloride medium. In the range of the total nickel concentration of 0.0145–1.000m, the emf data obtained could be explained in terms of the formation of the complex Ni4(OH)4 (the charge is omitted), the formation constant of the species being found to be log*β4,4=−28.55±0.10, together with some minor species NiOH (log*β1,1≤−10.5) and Ni2OH(log*β1,2≤−10.5).
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