Hydrological setting control 137Cs and 90Sr concentration at headwater catchments in the Chornobyl Exclusion Zone

Abstract

Concentration-discharge relationships are widely used to understand the hydrologic processes controlling river water chemistry. We investigated how hydrological processes affect radionuclide concentrations (137Cs and 90Sr) in surface water in the headwater catchment at the Chornobyl exclusion zone in Ukraine. In flat wetland catchment, the depth of saturated soil layer changed little throughout the year, but changes in saturated soil surface area during snowmelt and immediately after rainfall affected water chemistry by changing the opportunities for contact between suface water and the soil surface. On the other hand, slope catchments with little wetlands, the water chemistry in river water is formed by changes in the contribution of "shallow water" and "deep water" due to changes in the water pathways supplied to the river. Dissolved and suspended 137Cs concentrations did not correlate with discharge rate or competitive cations, but the solid/liquid ratio of 137Cs showed a significant negative relationship with water temperature, and further studies are needed in terms of sorption/desorption reactions. 90Sr concentrations in surface water were strongly related to water pathways for each the catchments. The contact between surface water and the soil surface and the change in the contribution of shallow and deep water to stream water could changes 90Sr concentrations in surface water for in wetland and slope catchments, respectively. In this study, we revealed that the radionuclide concentrations in rivers in Chornobyl is strongly affected by the water pathways at headwater catchments.