Abstract
A facile approach towards 4-halo-5,5-alkyl/aryl-N-phenyl-2-(trifluoromethyl)-2,5-dihydrofuran-2-amines by the reaction of readily available tertiary N-phenyl CF3-iminopropargylic alcohols with hydrohalic acids (HCl, HBr, HI) was developed. The obtained 4-halo-2,5-dihydrofurans were shown to readily undergo the reactions demonstrating their potential utility in the synthesis of various CF3-containing compounds.
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