Abstract

Numerous low-temperature geothermal waters are distributed extensively in Mangbang-Longling of western Yunnan in China, whose formation mechanism has not been completely investigated yet. This study focused on the hydrogeochemical evolution, reservoir temperature, and recharge origin of geothermal waters using hydrogeochemical and deuterium-oxygen (D-O) isotopic studies. The low-temperature geothermal waters were characterized by HCO3-Na type, while shallow cold spring was of the hydrochemical type of HCO3-Ca. The hydrogeochemical characteristics of low-temperature geothermal waters were mainly determined by the dissolution of silicate minerals based on the geological condition and correlations of major and minor ions. The reservoir temperatures of low-temperature geothermal waters ranged from 111°C to 126°C estimated by silica geothermometry and the silicon-enthalpy graphic method. Low-temperature geothermal waters circulated at the largest depth of 1794–2077 m where deep high-temperature geothermal waters were involved. The data points of δD and δ18O of the hot spring water samples in the study area show a linear right-up trend, indicating the δ18O reaction between the water and rock and a possible mixture of magmatic water from below. The low-temperature thermal waters were recharged by meteoric water at the elevation of 2362–3653 m calculated by δD values. Upwelling by heating energy, low-temperature geothermal waters were exposed as geothermal springs in the fault and fracture intersection and mixed by up to 72% shallow cold waters at surface. Based on acquired data, a conceptual model of the low-temperature geothermal waters in the Mangbang-Longling area was proposed for future exploitation.

Highlights

  • Energy shortage has been the serious problem for human beings globally due to explosive population growth, accelerated industrialization, and developed living standards [1]

  • It is noted fossil fuels will be consumed in decades, and renewable energy is expected to be the predominate energy in future

  • Erefore, we present hydrogeochemical and isotopic analyses for fourteen geothermal waters and one cold spring collected from the MangbangLongling area in western Yunnan. is study is aimed to the hydrogeochemical characteristic of geothermal and cold spring waters, clarify water-rock interaction, estimate reservoir temperature, and trace recharge source

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Summary

Introduction

Energy shortage has been the serious problem for human beings globally due to explosive population growth, accelerated industrialization, and developed living standards [1]. Western Yunnan possesses numerous and Journal of Chemistry widespread high- and low-temperature geothermal waters, representing an outstanding natural laboratory for investigating the genetic mechanism for the geothermal system [15]. Our new findings are expected to construct the genetic mechanism of the lowtemperature geothermal system, providing the reference for future management and sustainable exploitation of geothermal resource in the Mangbang-Longling area of western Yunnan. Study Area e Mangbang-Longling area is situated in western Yunnan, southwestern China (Figure 1) It is typical of subtropical monsoon climate with average annual air temperature of 14.8°C and mean annual rainfall of 1470 mm. High-temperature geothermal waters (hydrochemical type: Cl·HCO3-Na) are mostly assembled in the Rehai and Balazhang area, while low-medium temperature geothermal waters (hydrochemical type: HCO3-Na) are distributed dispersedly in the Mangbang-Longling area

Sampling and Methodology
Analytical Results
Discussion
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