Abstract

This paper presents the experimental results of cogasification of coal and biomass in an intermittent fluidized bed reactor, aiming to investigate the influences of operation parameters such as gasification temperature (T), steam to biomass mass ratio (SBMR), and biomass to coal mass ratio (BCMR) on hydrogen-rich (H2-rich) gas production. The results show that H2-rich gas free of N2 dilution is produced and the H2 yield is in the range of 18.25~68.13 g/kg. The increases of T, SBMR, and BCMR are all favorable for promoting the H2 production. Higher temperature contributes to higher CO and H2 contents, as well as H2 yield. The BCMR has a weak influence on gas composition, but the yield and content of H2 increase with BCMR, reaching a peak at the BCMR of 4. The H2 content and yield in the product gas increase with SBMR, whilst the content of CO increases first and then decreases correspondingly. At a typical case, the relative linear sensitivity coefficients of H2 production efficiency to T, SBMR, and BCMR were calculated. The results reveal that the order of the influence of the operation parameters on H2 production efficiency is T > SBMR > BCMR.

Highlights

  • Hydrogen is likely to be an important energy carrier in the future [1]

  • A sensitivity study was employed in order to provide a comparable measure of the influence of T, steam to biomass mass ratio (SBMR), and biomass to coal mass ratio (BCMR) on H2 production efficiency

  • The aim of this work was to investigate the influences of T, SBMR, and BCMR on H2-rich gas production by cogasification of coal and biomass in an intermittent fluidized bed

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Summary

Introduction

Hydrogen is likely to be an important energy carrier in the future [1]. the presence of hydrogen on Earth is limited to hydrogen-containing compounds and today, nearly 96% of hydrogen is produced from fossil fuels, which emit a large amount of carbon dioxide [2,3,4]. The fluidized bed reactor has been widely used as the biomass gasifier to produce hydrogen due to its various advantages which include better temperature control, wide feedstock adaptability, good gas solids contact, and excellent heat and mass transfer characteristics. Different gases such as air [7,8,9], pure steam [10,11,12], and air-steam [13, 14] can be adopted as the gasifying mediums

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