Abstract
Abstract High yield of value-added chemicals from lignin was always a big challenge on biomass utilization. A hydrogenolysis method of dealkaline lignin catalyzed by noble metal cooperated with metal chloride in methanol was proposed, producing high yields of aliphatic alcohols and aromatic monomers. The performances, especially the lignin liquefaction and product distribution were significantly affected by the catalysts, reaction temperature and time. 2.7% aliphatic alcohols and 17.4% monomers could be obtained at 280 °C for 5 h using Pd/C cooperated with CrCl3 under the optimized condition. Hydrogenolysis, condensation and methylation occurred simultaneously during the process. The condensation was preferred at excessive high temperature and prolonged time to form the residues.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
