Abstract
Bicyclic monoterpene epoxides, α-pinene oxide, 2,3-epoxybornane, α- and β-3,4-epoxycaranes were hydrogenated under high hydrogen pressure in the presence of Raney nickel catalyst. The products obtained were analysed by VPC and were identified by comparison with authentic samples. The effect of anions, OH −, Cl −, Br −, and I − for the hydrogenolysis was also examined. The results are summarized in the Tables. From the results, the structures of these bicyclic monoterpene epoxides, α-pinene oxide, 2,3-epoxybornane, α- and β-3,4-epoxycaranes were confirmed to be V, XII, XIX and XXI, respectively.
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