Abstract
Pd(OAc) 2 undergoes easy and quantitative coordination to a cross-linked styrene/divinylbenzene resin functionalized with bis(diphenylphosphino)methane ligands to yield a supported palladium complex which behaves as a versatile and recyclable heterogenized catalyst for the hydrogenation of nitrocompounds and α,β-unsaturated aldehydes under mild conditions. Whereas nitrobenzene is converted only into aniline, cinnamaldehyde is selectively converted into hydrocinnamaldehyde.
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