Abstract
AbstractActive titanium slurries, effective in the McMurry coupling reaction of ketones to olefins, are also hydrogenation agents. Sometimes they also promote isomerisation of the originally formed olefin as well as aldol type and pinacol type condensations under special reaction conditions.The most prominent factors promoting hydrogenation are the use of high ratios LiAlH4: TiCl3 and low temperatures in the formation of the low‐valent titanium species.
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