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Abstract
The transport behavior of n-decyl alcohol (C 10 OH) into hydrogenated polybutadienes (HPBD) (MW=100 000; M w /M n <1.1) with varied branch contents was investigated using a FTIR-ATR sampling method. A significant difference in crystallinities determined by DSC and density measurements was evident. A nonlinear dependence of the equilibrium sorption on the density of HPBDs was observed and an exponential dependence of diffusivities on the density of the polymers was evident. The observed transport behaviors deviate from those predicted using a simple two-phase model
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