Abstract
The kinetics of the hydrogen getter 1,4-bis(phenylethynyl)benzene (DEB) blended with carbon-supported Pd (DEB-Pd/C) dispersed uniformly in silicone [DEB-Pd/C-poly(dimethyl siloxane)] were studied with a thermogravimetric method as a function of the hydrogen pressure and temperature. A diffusion-controlled reaction model was developed to explain the experimental results. The diffusion coefficient, solubility coefficient, and permeability of hydrogen through silicone rubber were determined. © 2001 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 39: 425–431, 2001
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