Abstract

The anionic polymerization of the N-acylacrylamide derivatives 1 and 2 was carried out at 120 °C for 24 h in N,N-dimethylformamide by lithium tert-butoxide (t-BuOLi, 3 mol %) as an initiator to obtain polymers 3 and 4 in moderate yields. The obtained polymers selectively were composed of the hydrogen-transfer polymerization unit.

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