Hydrogen production from lignin, cellulose and waste biomass via supercritical water gasification: Catalyst activity and process optimization study

Abstract

Process optimization for catalytic biomass supercritical water gasification process (SCWG) was performed. By catalysts screening using cellulose and lignin as biomass model compounds, K2CO3 and 20Ni0.36Ce/Al2O3 were identified as the best catalysts. Then, an optimization study based on Taguchi experimental design was conducted, and waste biomass including wheat straw, canola meal, and timothy grass were used as feedstock. The effect of different parameters are studied. For these parameters, the order of relative importance for hydrogen production is: temperature>catalyst loading>catalyst type>biomass type. High temperature (∼650°C), and high catalyst loading (∼100%) are favorable for hydrogen production. The average hydrogen yield using different waste biomass was in the order of: canola meal>wheat straw>timothy grass.