Hydrogen Peroxide Tuned Morphology and Crystal Structure of Barium Vanadate-Based Nanostructures for Aqueous Zinc-Ion Storage Properties.

Abstract

Improving the layered-structure stability and suppressing vanadium (V) dissolution during repeated Zn2+ insertion/extraction processes are key to promoting the electrochemical stability of V-based cathodes for aqueous zinc (Zn)-ion batteries (AZIBs). In this study, barium vanadate (Ba2 V2 O7 , BVO) nanostructures (NSs) are synthesized using a facile hydrothermal method. The formation process of the BVO NSs is controlled by adjusting the concentration of hydrogen peroxide (H2 O2 ), and these NSs are employed as potential cathode materials for AZIBs. As the H2 O2 content increases, the corresponding electrochemical properties demonstrate a discernible parabolic trend, with an initial increase, followed by a subsequent decrease. Benefiting from the effect of H2 O2 concentration, the optimized BVO electrode with 20mL H2 O2 delivers a specific capacity of 180.15mAhg-1 at 1Ag-1 with good rate capability and a long-term cyclability of 158.34mAhg-1 at 3Ag-1 over 2000 cycles. Thus, this study provides a method for designing cathode materials with robust structures to boost the electrochemical performance of AZIBs.