Hydrogen isotope effects on the structural phase transition of NH 3BH 3

Abstract

A systematic study of the structural phase transition of NH 3BH 3 and of its fully deuterated analogue was performed combining DSC and anelastic spectroscopy measurements. The transition is accompanied by a latent heat, and therefore is of the 1st order. On the deuterated sample the enthalpy variation is reduced of more than 20%, from 1.29 to 1.01 kJ/mol and the transition is shifted by ∼1.5 K toward higher temperatures. Both NH 3BH 3 and ND 3BD 3 display a temperature hysteresis between cooling and heating, thus denoting that the phase transition is of first-order. In addition, this hysteresis is extremely small (∼0.5 K) indicating that the coexistence region between the two phases is very narrow. During isothermal ageing, the transformation of the low-temperature orthorhombic phase into the high-temperature tetragonal one occurs with a time constant of ∼16 min in NH 3BH 3 and ∼64 min in ND 3BD 3, evidencing a drastic slowing down of kinetics in the deuterated compound.