Hydrogen-Induced Ductility Loss in Cast Irons

Abstract

Effect of hydrogen-charging was investigated with respect to the tensile properties of three types of cast irons: JIS FCD400, FCD450 and FCD700. In this study, hydrogen charging led to a marked ductility loss in all the cast irons. The thermal desorption spectroscopy and the hydrogen microprint technique revealed that, in the hydrogen-charged specimens, most of solute hydrogen was diffusive and mainly segregated at graphite, graphite/matrix interface zone and pearlite. In the fracture process of non-charged specimen, neighboring graphites were interconnected with each other mainly by ductile dimple fracture. On the other hand, in the fracture process of hydrogen-charged specimen, the graphites were interconnected by cracks. The difference in the fracture morphology between the non-charged and the hydrogen-charged specimens is attributed to the presence of diffusive hydrogen in graphite and graphite/matrix interface. During early stage of fracture process in hydrogen-charged specimen, the interspace between graphite and matrix is filled with hydrogen gas, which leads to the ductility loss of matrix in the vicinity of graphite. Even after the initiation of crack from graphite, hydrogen is continuously outgassed from graphite and supplied to the crack tip. Therefore, concerning the hydrogen effect on the strength of cast irons, a role of subsurface graphite as a “local hydrogen supplier” should be taken into consideration.