Hydrogen-induced cracking of X70 steel affected by sulfate-reducing bacteria and cathodic potential: experiment and density functional theory study

Abstract

Submarine pipeline are often exposed to the risk of hydrogen embrittlement from the dual action of marine sulfate-reducing bacteria (SRB) and cathodic protection (CP). In this work, hydrogen permeation test, slow strain rate tensile (SSRT) experiments, and density functional theory (DFT) were used to explain the hydrogen embrittlement (HE) mechanism of subsea pipeline steel under the action of SRB and CP. When the applied CP potential is increased from −850 mV to −1200 mV, the hydrogen seepage current increases 1.8 times. And the tensile specimens pre-charged with hydrogen exhibit significant hydrogen embrittlement behavior. DFT calculations show that the increased concentration of hydrogen atoms on the material surface decreases the diffusion potential barrier, leading to a larger hydrogen seepage current. In addition, the aggregation of hydrogen atoms in the steel weakens the chemical bonds between Fe atoms, leading to hydrogen embrittlement.